Modulating the electron-transfer properties of a mixed-valence system through host–guest chemistry† †Electronic supplementary information (ESI) available: More experimental details, crystallographic data, ORTEP, and packing diagram, NMR titrations, Job Plots, calculated host–guest distances, SWV for addition of iodide. CCDC 1004247. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02799j

Bypassing the lack of reactivity of endo-substituted norbornenes with the catalytic rectification–insertion mechanism† †Electronic supplementary information (ESI): Experimental procedures, NMR characterization, kinetic plots, ORTEP diagrams and cif files. CCDC 1034345–1034348 and 1034422. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03575e

Reversible quantitative guest sensing via spin crossover of an iron(ii) triazole† †Electronic supplementary information (ESI) available: Synthetic details, NMR spectra, instrumentation, plus additional structural, magnetic and TGA information and diagrams. CCDC 1434103 and 1434104. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc04583e Click here for additional data file. Click here for additional data file.

Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups† †Electronic supplementary information (ESI) available: Experimental details. Additional views of the molecular structures from X-ray diffraction. Cyclic voltammograms of 2 and 3. Plots of calculated lowest energy transitions versus UV-visible absorption spectra. Variable-temperature emission and excitation spectra. Copies of all NMR spectra. Cartesian coordinates of all optimised geometries. CCDC 1010408–1010412. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02410a Click here for additional data file. Click here for additional data file.

Institut für Anorganische Chemie, Julius Hubland, 97074 Würzburg, Germany. E-ma School of Medicine, Pharmacy and Health, Stockton-on-Tees, TS17 6BH, UK Department of Chemistry, University of Tor M5S 3H6, Canada Institut für Organische Chemie, JuliusHubland, 97074 Würzburg, Germany † Electronic supplementary information Additional views of the molecular stru voltammograms of 2 and 3. Plots of ca...

Mechanism of the cooperative Si–H bond activation at Ru–S bonds† †Electronic supplementary information (ESI) available: Experimental procedures and computational details, characterization, crystallographic and quantum-chemical calculation data as well as NMR spectra. CCDC 1055362–1055364. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01035g

Institut für Chemie, Technische Universitä Berlin, Germany. E-mail: peter.hrobarik@ [email protected] Department of Chemistry, Graduate Scho Materials Science, Nagoya University, Furo-c † Electronic supplementary information ( and computational details, chara quantum-chemical calculation data 1055362–1055364. For ESI and crystallog format see DOI: 10.1039/c5sc01035g Cite this: Chem....

Multi-electron reactivity of a cofacial di-tin(ii) cryptand: partial reduction of sulfur and selenium and reversible generation of S3˙– † †Electronic supplementary information (ESI) available: Experimental procedures and crystallographic details. CCDC 1469593, 1469595 and 1469596. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc01754a Click here for additional data file. Click here for additional data file.

Department of Chemistry, Massachusetts I Avenue, Cambridge, MA, 02139-4307, USA. Department of Chemistry and Chemical Street, Cambridge, MA 02138-2902, USA. EDepartment of Chemistry, Queen's Univer Canada K7L 3N6. E-mail: [email protected] † Electronic supplementary information ( and crystallographic details. CCDC 14695 crystallographic data in CIF or o 10.1039/c6sc01754a Cite this: Chem. Sci., 20...